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← ScienceDuring catalytic converter overheating in a vehicle, which failure occurs because of platinum's state functions?
A)Increased NOx due to platinum sintering✓
B)Rh removal by converter blow-through
C)Uncombusted fuel from reduced flow
D)Sulfur poisoning exceeding catalyst lightoff
💡 Explanation
Platinum sintering reduces active sites because it experiences grain growth at high temperatures; the state functions determine equilibrium size. This limits catalytic activity, increasing NOx, because the platinum surface is less effective rather than issues of flow or poisoning.
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