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← ScienceWhich condition accelerates polymer chain scission in polyethylene, a degradation process?
A)Increased ultraviolet light exposure✓
B)Elevated hydrostatic pressure
C)Rapid annealing near Tg
D)Decreased oxidative catalyst surface area
💡 Explanation
Increased UV radiation causes chain scission through photo-oxidation, because photochemical reactions generate free radicals leading to chain breakage. These chains break randomly rather than cross-linking; therefore, degradation speeds up, rather than crosslinking strengthening the material.
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