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← ScienceWhich consequence results when a catalyst degrades, and reaction rate constant decreases in an electrochemical cell?
A)Overpotential increases; cell voltage lowers✓
B)Current efficiency asymptotically trends upward
C)Equilibrium potential becomes unstable
D)Charge transfer resistance undergoes dampening
💡 Explanation
Overpotential increases and cell voltage lowers because the catalyst degradation reduces its catalytic activity, therefore more energy input is needed since *Tafel kinetics* dominate, rather than thermodynamic equilibrium achieved at lower overpotentials with a functioning catalyst.
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