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← ScienceWhich consequence results when a packed-bed reactor's temperature fluctuates rapidly around the optimal value for a kinetically-controlled exothermic reaction?
A)Substantial increase in catalyst lifetime
B)Oscillations in product concentration✓
C)Equilibrium constant becomes more favorable
D)Reaction becomes mass-transfer limited
💡 Explanation
Oscillations in product concentration emerge due to thermal runaway. Thermal runaway causes a rapid rate increase at temperature peaks, quickly consumed reactants; a subsequent rate decrease follows during troughs because Arrhenius equation dictates temperature sensitivity. Because of this, thermal runaway drives product concentration swings, rather than equilibrium constant shifts or catalyst life prolongation.
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