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← ScienceWhich consequence results when mass transport limitations dominate in heterogeneous catalysis?
A)Observed rate constant decreases✓
B)Actual temperature becomes irrelevant
C)Activation energy will increase
D)Equilibrium constant undergoes no change
💡 Explanation
The observed rate constant decreases because external diffusion limits reactant supply to the catalyst surface; therefore, the experimental rate does not reflect intrinsic kinetics, rather than activation energy influence or equilibrium shifts without catalyst influence.
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