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← ScienceWhich consequence results when variational wave functions poorly approximate true eigenfunctions?
A)Spurious energy minima are predicted✓
B)Improved computational efficiency occurs
C)Accurate excited state energies result
D)Simplified Hamiltonian operators are derived
💡 Explanation
When trial wave functions poorly represent eigenfunctions, the energy calculation from the variational method can become unstable, because error in the functions causes the minimization to find false minima rather than the real ground state; therefore option A, rather than improvements or accuracy.
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