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Which mechanism allows electron excitation between mismatched orbitals?

A)Quantum tunneling through virtual photons
B)Relativistic spin-orbit coupling realignment
C)Van der Waals radius superposition
D)Dipole-dipole induced electromagnetic shielding

💡 Explanation

Quantum tunneling involves electrons penetrating potential barriers via virtual photons leading to orbital excitation, because the uncertainty principle allows short-term energy non-conservation. Therefore, mismatched orbitals interact via tunneling, rather than through direct overlap, influenced by shielding alone.

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