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← ScienceWhich mechanism causes lowered solar cell efficiency because of grain boundaries?
A)Increased electron-hole recombination rate✓
B)Decreased built-in potential magnitude
C)Phonon scattering reduction lattice order
D)Reduced band gap at surfaces
💡 Explanation
Increased electron-hole recombination decreases efficiency because the grain boundaries disrupts the crystal lattice periodicity, enabling non-radiative transitions via the Shockley-Read-Hall recombination mechanism; therefore fewer photo-generated carriers reach contacts, rather than increased carrier momentum.
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