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Which mechanism causes the decreased elasticity observed in vulcanized rubber exposed to elevated temperatures?

A)Scission of polysulfide cross-links
B)Crystallization of polymer chains
C)Oxidation of unsaturated carbon bonds
D)Increased chain entanglement

💡 Explanation

When vulcanized rubber is heated, dissociation of polysulfide crosslinks occurs because thermal energy overcomes bond strength causing chain segments to become free and leading to loss of elasticity. Therefore scission of cross-links result, rather oxidation, etanglement, or crystalisation occurring which involving different mechanisms.

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