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← ScienceWhich mechanism compromises the structural integrity of epoxy adhesives at elevated temperatures?
A)Thermally-induced hydrolytic degradation✓
B)Increased London dispersion forces
C)Hydrogen dissociation equilibria shift
D)Crystal phase transition occurs
💡 Explanation
Elevated temperatures accelerate moisture permeation and therefore cause thermally-induced hydrolytic degradation of the ester linkages in the epoxy. This scission weakens the polymer matrix, because hydrolysis breaks the covalent bonds rather than just disrupting intermolecular forces.
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