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← ScienceWhich mechanism influences electrical conductivity when doping titanium dioxide nanoparticles with niobium ions?
A)Increased polaron hopping probability✓
B)Stabilization of rutile crystal structure
C)Formation of insulating grain boundaries
D)Increased electron-phonon scattering rate
💡 Explanation
When doping TiO2 nanoparticles with Nb5+ ions, charge compensation occurs via the creation of Ti3+ ions allowing electron polaron hopping between Ti4+ and Ti3+ sites since Nb substitutes for Ti without changing oxidation state and introduces mobile charge carriers. Therefore, increased polaron hopping occurs, rather than other options requiring alternate mechanisms or structural effects.
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