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Which mechanism initiates peroxide formation when tetrahydrofuran is exposed to air?

A)Molecular orbital mediated radical reaction
B)Electrophilic aromatic substitution catalysis
C)Transition metal complex oxidation
D)Electrostatic attraction driven solvation

💡 Explanation

Molecular oxygen reacts with tetrahydrofuran through a molecular orbital mediated radical reaction, forming unstable peroxides because the high-energy radicals readily abstract hydrogen atoms. Therefore, peroxides accumulate, rather than stable byproducts that would form under controlled reaction conditions.

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