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← ScienceWhich mechanism limits the maximum operating temperature of epoxy adhesives in structural composites?
A)Hydrolysis weakening ester linkages
B)Oxidation forming peroxy radicals
C)Glass transition enabling chain mobility✓
D)Crystallization increasing material brittleness
💡 Explanation
When temperature rises, the epoxy reaches its glass transition temperature (Tg), where increased chain mobility reduces secondary intermolecular forces, causing a dramatic drop in the adhesive's modulus and strength. Therefore the glass transition limits operating temperature, rather than hydrolysis, oxidation or crystallization which occur via alternative mechanisms or produce different effects.
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