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Which mechanism restricts the maximum operating temperature of a polymer electrolyte membrane fuel cell (PEMFC)?

A)Electrolyte dehydration from low humidity
B)Carbon corrosion from catalyst oxidation
C)Membrane swelling from excessive humidity
D)Electrode delamination from thermal expansion mismatch

💡 Explanation

When temperature increases and humidity decreases, the membrane loses water through evaporation because vapor pressure rises, reducing proton conductivity significantly and thus cell performance. Therefore, electrolyte dehydration results, rather than carbon corrosion, swelling, or delamination, which involve alternative degradation mechanisms at higher temperatures or different causes.

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