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Which outcome occurs in a molecule when an electron transitions between antibonding and bonding orbitals following photoexcitation?

A)Increased bond order and stability
B)Decreased vibrational frequency and amplitude
C)Electron spin flip causing paramagnetism
D)Accelerated rate of intersystem crossing

💡 Explanation

When photoexcitation promotes an electron from an antibonding to a bonding orbital, bond order increases because bonding orbitals contribute positively to bond order while antibonding orbitals contribute negatively, leading to increased stability. Therefore, increased bond order and stability results, rather than changes dependent on vibrational modes, spin flips, or intersystem crossing efficiency.

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