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← ScienceWhich outcome occurs when a catalyst becomes poisoned in a chemical reactor operating at high temperature?
A)Global reaction rate decreases markedly✓
B)Equilibrium constant shifts unfavorably
C)Selectivity toward desired product increases
D)Reactor pressure decreases due to adsorption
💡 Explanation
When a catalyst is poisoned, active sites are blocked by contaminants, hindering reactant adsorption via competitive inhibition because the rate constant becomes limited, causing a decrease in the overall reaction rate. Therefore reaction rate diminishes significantly, rather than equilibrium shift, selectivity increase, or pressure decrease, which rely on other parameters.
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