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← ScienceWhich process initiates phosphorescence in a metal-ligand complex?
A)Intersystem crossing fills triplet states✓
B)Vibrational relaxation forms a cascade
C)Ligand exchange halts electronic transitions
D)Metal oxidation quenches all emission
💡 Explanation
Intersystem crossing causes phosphorescence because it allows a transition from a singlet excited state to a triplet state with a longer lifetime, therefore emission persists rather than fluorescence which decays rapidly.
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