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Which process limits maximum current density in solid-state catalyst electrodes under electrochemical oxidation?

A)Joule heating of the electrode matrix
B)Depletion of reactive surface intermediates
C)Electrolyte conductivity near the electrode
D)Recombination rate of electron-hole pairs

💡 Explanation

When electrochemical oxidation proceeds, depletion of reactive surface intermediates occurs due to product formation and diffusion limitations, which decreases availability for subsequent reaction, limiting current density. Therefore surface intermediate depletion is the limit, rather than joule heating, electrolyte conductivity, or recombination which occur via different mechanisms with independent conditions.

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