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← ScienceWhich process limits reaction rate when reactant molecular orbital symmetry is incompatible?
A)Increased activation energy barrier✓
B)Reduced steric hindrance interaction
C)Elevated Boltzmann distribution fraction
D)Decreased collision frequency factor
💡 Explanation
When reactant molecular orbital symmetry is incompatible, orbital overlap is inhibited, leading to an increased activation energy barrier because the transition state stabilization is lessened. Therefore an increased activation energy barrier is the limiting factor, rather than altered steric hindrance, Boltzmann distribution, or collision frequency, which relate to different reaction limitations.
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