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Which thermodynamic consequence results when a hydrocarbon feedstock spontaneously transitions from liquid to vapor within a distillation column?

A)Reduced separation efficiency from non-equilibrium
B)Increased system pressure due to volume reduction
C)Decreased column temperature from adiabatic compression
D)Enhanced product purity from increased reflux ratio

💡 Explanation

When a liquid hydrocarbon flashes to vapor, non-equilibrium conditions arise due to rapid changes in composition and temperature; this phase transition increases entropy and minimizes effective separation, thereby disrupting steady-state operation of mass transfer unit. Therefore separation efficiency decreases, rather than increased pressure, lower temperature, or enhanced reflux requiring different process conditions.

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