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Physical Sciences & Mathematics

A concentration cell comprises two copper electrodes immersed in differing concentrations of copper(II) sulfate solution. Why does the electrode in the more dilute solution act as the anode?

A)Cupric ions favor precipitation there.
B)Lower ion activity reduces reduction.
C)Oxidation restores ion concentration.
D)Sulfate ions attract more electrons.

💡 Explanation

The electrode in the more dilute solution acts as the anode because oxidation at that electrode increases the concentration of Cu2+ ions, counteracting the concentration difference; this drives the cell reaction. Therefore, oxidation must occur to balance the concentrations, rather than reduction dominating.

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