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← ScienceWhich mechanism closes the band gap when applying intense pressure to germanium?
A)Increased orbital wavefunction overlap✓
B)Decreased electron-phonon scattering
C)Enhanced Umklapp scattering events
D)Reduced piezoelectric polarization
💡 Explanation
Increased pressure forces atoms closer, enhancing the orbital wavefunction overlap, which broadens the energy bands and reduce the band gap, eventually closing it; therefore orbital overlap is increased rather than electron scattering affecting band closure.
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