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Which outcome diminishes catalyst effectiveness after prolonged use in three-way catalytic converters?

A)Active site surface area decreases
B)Increased support material surface area
C)Reactant concentration gradients equilibrate
D)Elevated exhaust gas total enthalpy

💡 Explanation

Reduced catalytic activity follows from catalyst poisoning. Decreased surface area through sintering lowers active surface sites, because the precious metals cluster and reduce effective platinum group exposure; therefore, conversion rates decline dramatically rather than increasing them via dispersion or enthalpy effects.

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