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← HistoryWhich risk increased significantly in ancient bronze foundries when furnace atmospheres became less oxidizing?
A)Increased tin oxide volatilization losses
B)Reduced CO off-gas concentrations
C)Phosphorus embrittlement becoming prevalent✓
D)Increased copper oxide inclusion formation
💡 Explanation
Phosphorus present in some copper ores wasn't effectively oxidized/removed; instead, phosphorus diffused faster causing grain boundary segregation (phosphorus embrittlement). This occurred more easily rather than oxidation of phosphorus because the atmosphere was reducing; therefore making the bronze prone more brittle during casting than other effects.
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